Oxidative transformation of thiols to disulfides promoted by activated carbon-air system |
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Authors: | Masahiko Hayashi Ken-ichi Okunaga Shunsuke Nishida Kenjiro Kawamura Kazuo Eda |
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Affiliation: | Department of Chemistry, Graduate School of Science, Kobe University, Kobe 657-8501, Japan |
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Abstract: | Efficient oxidative transformation of thiols to disulfides took place in the presence of activated carbon under an oxygen (or air) atmosphere. The present oxidation method is available not only for a variety of thiols such as simple aromatic and aliphatic thiols but also for 3,4-dihydropyrimidin-2(1H)-thiones and N-Boc-l-cysteine. |
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Keywords: | Activated carbon Oxidation Thiol Disulfide |
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