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Effect of deuterated solvents toward 2,2,2-trichloroethyl esters with a benzylic methylene moiety |
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| Authors: | Tomoko Mineno Haruyasu Hirayama Mitsuaki Yamashita Hiroshi Moriwaki |
| Affiliation: | a Laboratory of Medicinal Chemistry, Faculty of Pharmacy, Takasaki University of Health and Welfare, 60 Nakaorui, Takasaki, Gunma 370-0033, Japan b Laboratory of Organic Chemistry for Life Sciences, Faculty of Pharmacy, Takasaki University of Health and Welfare, 60 Nakaorui, Takasaki, Gunma 370-0033, Japan c Laboratory of Organic Chemistry, Faculty of Pharmaceutical Sciences, Sojo University, 4-22-1 Ikeda, Kumamoto 860-0082, Japan d Division of Applied Biology, Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokita, Ueda, Nagano 386-8567, Japan |
| Abstract: | The indium-promoted chemoselective deprotection of 2,2,2-trichloroethyl esters containing a benzylic methylene was successfully achieved by employing deuterated solvents. |
| Keywords: | 2,2,2-Trichloroethyl esters Benzylic methylene moiety Deuterated solvents Indium |
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