Enantiospecific synthesis of sex pheromone of the obscure mealybug from pantolactone via tandem conjugate addition/cyclization |
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| Authors: | Atul K. Hajare |
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| Affiliation: | Discovery Chemistry, Advinus Therapeutics Pvt. Ltd, Quantum Towers, Plot No. 9, Rajiv Gandhi Infotech Park, Phase-I, Hinjewadi, Pune 411057, India |
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| Abstract: | An efficient synthesis of an enantiomer of insect’s natural pheromone is reported starting from chiral pool d-(−)-pantolactone. Highly stereoselective tandem conjugate addition/cyclization sequence and hydrogenation of exocyclic double bond are the key steps in the present synthesis. |
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| Keywords: | Pheromone Enantiospecific synthesis Tandem reaction Pantolactone |
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