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Reductive carboxylation of alkyl halides with CO2 by use of photoinduced SmI2/Sm reduction system |
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| Authors: | Akihiro Nomoto Go Shiino Ikuko Mitani Akiya Ogawa |
| Institution: | a Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan b Environmental Research Center, Power Engineering R&D Center, The Kansai Electric Power Co., Inc., 1-7 Hikaridai, Seika-cho, Soraku-gun, Kyoto 619-0237, Japan |
| Abstract: | Upon visible-light irradiation, reductive carboxylation of alkyl halides takes place by using a SmI2/Sm mixed system under atmospheric CO2 to afford the corresponding carboxylic acids in good to excellent yields. |
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