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掺铜五氧化二钒的制备及电化学性能研究
引用本文:余艳丽,刘恒,杨为中. 掺铜五氧化二钒的制备及电化学性能研究[J]. 化学研究与应用, 2008, 20(8)
作者姓名:余艳丽  刘恒  杨为中
作者单位:四川大学材料科学与工程学院,四川,成都,610064;四川大学材料科学与工程学院,四川,成都,610064;四川大学材料科学与工程学院,四川,成都,610064
摘    要:锂离子电池由于具有比能量和放电电压高,自放电小,无记忆效应和循环稳定性好等特性已被广泛应用于手机电池,笔记本电脑,电动玩具,电动自行车等许多领域[1,2].

关 键 词:五氧化二钒  铜掺杂  电化学性能  锂离子电池  正极材料

Study on the preparation of Cu-dopped-V2O5 and its electrochemical performance
YU Yan-li,LIU Heng,YANG Wei-zhong. Study on the preparation of Cu-dopped-V2O5 and its electrochemical performance[J]. Chemical Research and Application, 2008, 20(8)
Authors:YU Yan-li  LIU Heng  YANG Wei-zhong
Abstract:Crystalline Cu-doped V2O5 particles were prepared by the liquid precipitation method.The crystal structure,morphology and electrochemical performance of the Cu0.1V2O5 particles were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),and galvanostatic cycling.XRD results indicate that Cu-doped V2O5 exhibited the same orthorhombic structure as that of un-doped V2O5.The results of galvanostatic cycling for samples show that Cu-doped V2O5 has a better electrochemical behavior.The active materials maintain the specific capacity of 185 mAhg-1 at C/5 rate over the voltage range of 2-4V after 20 cycles.
Keywords:vanadium pentoxide  cu-doping  eectrochemical properties  lithium-ion battery  cathode material
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