N.M.R. and I.R. studies of 1, 1, 1 trifluoroacetone in proton donor solvents |
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Authors: | C. L. Khetrapal M. M. Dhingra V. B. Kartha |
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Affiliation: | 1. Tata Institute of Fundamental Research, Bombay-5 2. Bhabha Atomic Research Centre, Bombay
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Abstract: | Interactions of 1, 1, 1 trifluoroacetone with proton donor solvents of the type RH [where R=HO, CH3S, CH3CH2CH2CH2S, CH3O, (CH3)2N, (C2H5)2N] have been investigated using NMR and infra-red techniques. Evidence of the formation of addition products of the type CF3.C(OH)R.CH3 where OH group is hydrogen-bonded with the fluorine of the CF3 group has been obtained. |
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