Organothallium compounds. Mechanistic study of the disproportionation reaction of organothallium compounds with copper in acetonitrile |
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| Authors: | I. F. Gun'kin |
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| Affiliation: | (1) Politechnical Institute, 410016 Saratov, Russian Federation |
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| Abstract: | Disproportionation reactions of various phenyl- and thienylthallium dicarboxylates with copper in acetonitrile have been carried out. The reaction mechanism proposed involves the participation of the ArTl2+ dication and various cationic pairs of the dication and the intermediate formation of organothallium radicals.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1970–1973, November, 1993. |
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| Keywords: | organothallium compounds disproportionation reaction with copper mechanism phenylthallium and thienylthallium dicarboxylates organothallium radicals, dications |
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