Crystal structures,optical properties and theoretical calculation of novel two-photon polymerization initiators |
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Authors: | Hong-Ping Zhou Dong-Mei Li Ju-Zhou Zhang Yong-Min Zhu Jie-Ying Wu Zhang-Jun Hu Jia-Xiang Yang Gui-Bao Xu Yu-Peng Tian Yi Xie Xu-Tang Tao Min-Hua Jiang Li-Min Tao Ya-Hui Guo Chuan-Kui Wang |
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Institution: | 1. Department of Chemistry, Anhui University, 230039 Hefei, PR China;2. Department of Chemistry, University of Science and Technology of China, 230026 Hefei, PR China;3. State Key Laboratory of Crystal Materials, Shandong University, 250100 Jinan, PR China;4. Department of Physics, Shandong Normal University, 250100 Jinan, PR China |
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Abstract: | Three novel A–π–D–π–A type compounds 3,6-bis2-(4-pyridyl)ethenyl]-9-ethylcarbazole (1), 3,6-bis2-(2-pyridyl)ethenyl]-9-ethylcarbazole (2), 3,6-bis2-(4-pyridyl)ethenyl]-9-ethylpyridylcarbazole (3) were conveniently synthesized by Pd-catalyzed Heck coupling methodology and characterized by single crystal X-ray diffraction determination. One-photon fluorescence, one-photon fluorescence quantum yields, one-photon fluorescence lifetime, and two-photon fluorescence have been investigated. The calculated two-photon absorption cross-sections for the three initiators by quantum chemical method are as high as 947, 943 and 815 × 10−50 cm4 s photon−1, respectively. Two-photon initiating polymerization microfabrication experiments have been carried out and the possible polymerization mechanism was also discussed. The results show that they are good two-photon absorbing chromophores and effective two-photon photopolymerization initiators. |
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Keywords: | X-ray diffraction Heck reaction Two-photon microfabrication |
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