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Copolymerization of N-allenylimidazole with di(ethylene glycol) divinyl ether and complexation of the copolymers with CuCl2 |
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| Authors: | L. V. Morozova I. V. Tatarinova N. P. Kuznetsova M. V. Markova O. A. Tarasova L. M. Sinegovskaya T. I. Vakul’skaya A. I. Mikhaleva B. A. Trofimov |
| Affiliation: | (1) A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033 Irkutsk, Russian Federation |
| Abstract: | Polyfunctionalized linear copolymers of N-allenylimidazole and di(ethylene glycol) divinyl ether with polyconjugated (polyvinylene) blocks in the main chain and exomethylene bonds and vinyloxyethoxyethyl groups in the side chain were prepared. Using the reaction of the copolymers with CuCl2, a possibility of synthesis of polymeric metal complexes for catalysis of organic reactions was shown. The IR and ESR spectra of the complexes were studied. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 973–977, June, 2006. |
| Keywords: | N-allenylimidazole di(ethylene glycol) divinyl ether copolymerization metal complexes IR spectra ESR spectra |
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