Reactivity control of an allylsilane bearing a 2-(phenylazo)phenyl group by photoswitching of the coordination number of silicon |
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| Authors: | Kano Naokazu Yamamura Masaki Kawashima Takayuki |
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| Institution: | Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. |
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| Abstract: | Photoswitching of the coordination number of silicon between four and five in allyldifluoro2-(phenylazo)phenyl]silane, which was confirmed by X-ray analysis and multinuclear NMR spectroscopy, caused multistep reactions to proceed or stop, yielding tetrafluoro2-(1-allyl-2-phenylhydrazino)phenyl]silicate without altering other reaction conditions. |
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