Discrete water hexamers and template-assisted molecular recognition in an elastic zincophosphate lattice |
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Authors: | Liao Yueh-Chun Jiang Yao-Chen Wang Sue-Lein |
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Affiliation: | Department of Chemistry, National Tsing Hua University Hsinchu 30043, Taiwan. |
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Abstract: | Water molecules and terephthalic acid, respectively, exist as a self-assembled monolayer of cyclic (H2O)6 clusters and (TA)infinity chiral chains between the zincophosphate sheets (in blue wires); the irremovable template H3tren3+ ions (in purple wires) are dynamic and could translate back and forth on the sheets during the conversion of the supramolecule contained in one another. |
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