Electrochemical chlorination of ethyl acetoacetate and the formation of ethyl 2,2,4-trichloroacetoacetate |
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Authors: | V. A. Ilyushin V. G. Malaev |
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Affiliation: | (1) A. N. Frumkin Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions The electrochemical chlorination of ethyl acetoacetate in aqueous media proceeds at C2 and, partially, at C4 to give ethyl 2,2-dichloroacetoacetate and small amounts of ethyl 2,2,4-trichloroacetoacetate.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 876–877, April, 1988. |
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