Ruthenium trihydrides with N-heterocyclic carbene ligands: effects on quantum mechanical exchange coupling |
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Authors: | Jones Aled L McGrady G Sean Sirsch Peter Steed Jonathan W |
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Affiliation: | Department of Chemistry, University of New Brunswick, Fredericton, N.B., CanadaE3B 6E2. |
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Abstract: | Ruthenium trihydrides containing N-heterocyclic carbene ligands display large quantum mechanical exchange couplings in their 1H NMR spectra: DFT calculations are used to explore this phenomenon and to compare them to their phosphine congeners. |
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