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Ruthenium trihydrides with N-heterocyclic carbene ligands: effects on quantum mechanical exchange coupling
Authors:Jones Aled L  McGrady G Sean  Sirsch Peter  Steed Jonathan W
Affiliation:Department of Chemistry, University of New Brunswick, Fredericton, N.B., CanadaE3B 6E2.
Abstract:Ruthenium trihydrides containing N-heterocyclic carbene ligands display large quantum mechanical exchange couplings in their 1H NMR spectra: DFT calculations are used to explore this phenomenon and to compare them to their phosphine congeners.
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