| A novel regio-and stereo-specific hydrohalogenation reaction of 2-alkynoic acids and their derivatives |
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| 基金项目： | Project supported by the National Natural Science Foundation of China and Chinese Academy of Sciences. |
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| 摘 要： | The nucleophilic hydrohalogenation of 2-alkynoic acids anti their derivatives byheating with lithium halides iu HOAc afforded the thermodynamically unfavorable 3-halo-2 (Z)-alkenoic acids and their derivatives stereospecifically
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A novel regio- and stereo-specific hydrohalogenation reaction of 2-alkynoic acids and their derivatives |
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| Authors: | Xi-Yan Lu Guo-Xin Zhu Sheng-Ming Ma |
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| Abstract: | The nucleophilic hydrohalogenation of 2-alkynoic acids and their derivatives by heating with lithium halides in HOAc afforded the thermodynamically unfavorable 3-halo-2 (Z)-alkenoic acids and their derivatives stereospecifically |
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