Crystal Structure and IR Study of (C6H5NH3)[ZnCl(HPO3)] |
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| Authors: | Souad Chaouche Rachid Ouarsal Mohammed Lachkar Francesco Capitelli Brahim El Bali |
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| Affiliation: | 1.Laboratoire d’Ingénierie des Matériaux Organométalliques et Moléculaires, Département de Chimie, Faculté des Sciences,Université Sidi Mohamed Ben Abdellah,Fès,Morocco;2.Institute of Crystallography–CNR,Bari,Italy;3.Laboratory of Mineral Solid and Analytical Chemistry “LMSAC”, Department of Chemistry, Faculty of Sciences,University Mohamed I,Oujda,Morocco |
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| Abstract: | Abstract A new hybrid phosphate, (C6H5NH3)[ZnCl(HPO3)], has been synthesized and its structure characterized from single-crystal X-ray diffraction. The title compound crystallizes in the orthorhombic space group Pbca (n. 61) with the unit-cell parameters: a = 9.8635(2) ?, b = 9.4516(10) ?, c = 22.2430(4) ?, Z = 8 and V = 2,073.62(6) ?3. The final R factors were R/ωR = 0.0361/0.0924. Its framework might be described as a layered structure with two (010)-parallel cationic and anionic layers. The IR spectrum of this phase shows characteristic bands of phosphite and anilinium groups. |
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