Crystallochemical causes of the different thermal properties of [Cu(py)2(NCS)2] and [Cu(4-Mepy)2(NCS)2] complexes |
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| Authors: | M Kabe?ová Z Kozf?ková M Dunaj-Jurco |
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| Institution: | 1. Department of Inorganic Chemistry, Slovak Technical University, 812 37, Bratislava, Czech and Slovak F. R.
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| Abstract: | The crystal structures and thermal behaviour of Cu(py)2(NCS)2] (at 293) and Cu(4-Mepy)2(NCS)2] and 180 K) complexes have been compared with their different temperature behaviour. It was found that the thermal stability of coordinated thiocyanate ligands in the course of thermal decomposition depends not only on the properties of the ligand L, but it is related to the arrangement of the thiocyanatocopper chains in the crystal structures. |
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