A novel hexaaza macrocyclic complex [CuL](ClO4)2 |
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| Authors: | S. Ren S. L. Ma |
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| Affiliation: | 1.Department of Application Chemistry, College of Science,Tianjin University of Commerce,Tianjin,P.R. China |
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| Abstract: | A novel N4-planar Cu(II) macrocyclic fragment, namely, [CuL](ClO4)2 (I) (L = 4-methyl-1,3,6,8,11,14-hexaazatricyclo[12.2.1.18,11)octadecane has been prepared from a simple template condensation reaction and structurally characterized for the first time. The complex of I crystallizes in the monoclinic system of space group P21/c with unit cell parameters: a = 17.124(10), b = 9.255(5), c = 14.053(8) Å and β = 111.262(7)°. |
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