Stereoselective synthesis of P-chirogenic dibenzophosphole-boranes via aryne intermediates |
| |
| Authors: | Diemer Vincent Berthelot Anaïs Bayardon Jérôme Jugé Sylvain Leroux Frédéric R Colobert Françoise |
| |
| Affiliation: | Laboratoire de Chimie Moléculaire (UMR CNRS 7509), Université de Strasbourg, ECPM, 25 rue Becquerel, 67087 Strasbourg, France. |
| |
| Abstract: | A new aryne-mediated tandem cross-coupling/P-cyclization sequence starting from tertiary phosphine-boranes and 1,2-dibromobenzenes is reported. P-chirogenic dibenzophospholes become accessible in a regio-, chemo-, and diastereoselective way. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
