A novel 9-MC-3 and 15-MC-6 onset stacked metallacrown single-molecule magnet: synthesis and crystal structure |
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| Authors: | Wang Suna Kong Lingqian Yang Hua He Zhoutong Jiang Zheng Li Dacheng Zeng Suyuan Niu Meiju Song You Dou Jianmin |
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| Institution: | School of Chemistry and Chemical Engineering, Liaocheng University, 252059 Liaocheng, People's Republic of China. |
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| Abstract: | A novel enneanuclear manganese complex, Mn(9)O(4)(Mesao)(6)(MeO)(3)(O(2)CMe)(3)(OH)(MeOH)(2)]·2.5DMF 1; Me-saoH(2) = 2-hydroxyphenylethanone oxime], was synthesized. The structure of 1 contains an unusual Mn(9)O(4)] core with an unprecedented defective "supertetrahedron" topology based on two parallel, onset stacked 9-MC-3 and 15-MC-6 metallacrown subunits. Magnetic studies indicate that 1 behaves as a single-molecule magnet. |
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