A sodalite-type porous metal-organic framework with polyoxometalate templates: adsorption and decomposition of dimethyl methylphosphonate |
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| Authors: | Ma Feng-Ji Liu Shu-Xia Sun Chun-Yan Liang Da-Dong Ren Guo-Jian Wei Feng Chen Ya-Guang Su Zhong-Min |
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| Affiliation: | Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China. |
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| Abstract: | A sodalite-type porous metal-organic framework with polyoxometalate templates, H(3)[(Cu(4)Cl)(3)(BTC)(8)](2)[PW(12)O(40)]·(C(4)H(12)N)(6)·3H(2)O (NENU-11; BTC = 1,3,5-benzenetricarboxylate), was obtained by a hydrothermal reaction. As a reasonable candidate for eliminating nerve gas, NENU-11 displays good adsorption behavior for dimethyl methylphosphonate (15.5 molecules per formula unit). In virtue of the catalytic activity of polyoxometalate guests, this nerve gas mimic could be facilely decomposed by a hydrolysis reaction. |
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