Oxidation of 4-Nitrotoluene by Ozone in Acetic Anhydride in the Presence of Manganese Sulfate |
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Authors: | Potapenko E. V. Galstyan G. A. Galstyan A. G. Kudyukov Yu. P. |
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Affiliation: | (1) Rubezhnoe Branch, East Ukrainian State University, Rubezhnoe, Lugansk region, Ukraine |
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Abstract: | The reaction of 4-nitrotoluene oxidation with ozone in acetic anhydride in the presence of MnSO4and sulfuric acid was studied. The main reaction product is 4-nitrobenzyl acetate, the yield of which is 63.2%. Based on an analysis of the experimental data, a mechanism of the catalytic ozonation of 4-nitrotoluene in acetic anhydride was proposed. |
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