Redox-active cross-linkable poly(ionic liquid)s |
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| Authors: | Sui Xiaofeng Hempenius Mark A Vancso G Julius |
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| Institution: | Materials Science and Technology of Polymers, MESA+ Institute for Nanotechnology, University of Twente, 7500 AE Enschede, The Netherlands. |
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| Abstract: | The synthesis of a new class of cross-linkable redox-responsive poly(ferrocenylsilane)-based poly(ionic liquid)s (PFS-PILs) is reported. PFS-PILs self-cross-link at low concentrations into nanogels or form macroscopic hydrogel networks at higher concentrations. PFS-PILs proved to be efficient dispersants in the microemulsion polymerization of methyl methacrylate, producing stable PFS-poly(methyl methacrylate) latex suspensions. |
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