Reaction of chlorine fluorosulfate with 1-trifluoromethoxy-1,2-dichlorotrifluoroethane and 1,2-dichlorohexafluoropropane |
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| Authors: | A V Fokin Yu N Studnev A I Rapkin A S Tatarinov K I Pasevina |
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| Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The reactivity of chlorine fluorosulfate increases with increasing acidity of the medium. In HSO3F/SbF5, chlorine fluorosulfate under mild conditions replaces the terminal chlorine atom in 1,2-dichlorohexafluoropropane and both chlorine atoms in 1-trifluoromethoxy-1,2-dichlorotrifluoroethane by fluorosulfate groups.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1669–1672, July, 1985. |
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