A new route for the synthesis of 4,5-diamino-6-arylsulfanylpyrimidine derivatives and also purines on their basis |
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Authors: | C. V. Popil’nichenko R. N. Solomyannyj V. S. Brovarets |
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Affiliation: | (1) Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 1 Murmanska St., Kyiv, 02660, Ukraine; |
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Abstract: | 5-Acylamino-4-amino-6-arylsulfanylpyrimidines were formed by the reaction 3-arylsulfanyl-2-acylami- no-3-chloroacrylonitriles with benzamidine. The products were converted into new derivatives of 6-aryl- sulfanyl-substituted purine bases by treatment with polyphosphoric acid. |
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