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Mechanical composites based on biologically active compounds from larch wood
Authors:E. N. Medvedeva  N. A. Neverova  L. A. Ostroukhova  V. A. Babkin  S. A. Gus’kov  E. S. Meteleva  A. V. Dushkin
Affiliation:(1) Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo, 1, 664033 Irkutsk, Russia;(2) Institute of Solid-State and Mechanical Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Kutateladze, 18, Novosibirsk, Russia
Abstract:Mechanical composites were prepared by mechanical chemical processing of a mixture of biologically active preparations of arabinogalactan (AG) and dihydroquercetin (DQ) isolated from larch wood. Their properties were studied using HPLC, 13C NMR, and IR spectroscopy. It was found that AG and DQ did not react chemically under the studied conditions. According to x-ray phase and thermal analyses, mechanical processing destroyed the DQ crystalline structure and dispersed it into the AG matrix. The resulting mechanical composites had significantly higher (up to 38 times) solubility in water compared with starting DQ and an unprocessed AG/DQ mixture. It was shown that DQ reduces the extent of destruction of polysaccharide macromolecules during mechanical processing.
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