Complexation of copper(II) with 3-(2-hydroxyphenylazo)pentadione-2,4 |
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Authors: | S R Gadzhieva T M Mursalov K T Makhmudov F G Pashaev F M Chyragov |
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Institution: | (1) Faculty of Chemistry, Baku State University, ul. Khalilova 23, Baku, Az1148, Azerbaijan |
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Abstract: | It is shown that 3-(2-hydroxyphenylazo)pentadione-2,4 (H2L) can exist in three tautomeric forms (enol-azo, keto-azo, and hydrazo). The effective atomic charges in the tautomeric forms of H2L are calculated by the Hückel MO LCAO method. The molar fractions and molar absorptivities of the tautomers at different pH are found. The complexation of copper(II) with H2L is studied by spectrophotometry. Beer’s law is obeyed for 0.51–5.12 µg/mL of copper. The assumed complex structure is given. The effect of foreign ions and masking agents on the complexation is studied. A procedure for the photometric determination of copper(II) in zinc-based alloys is proposed. |
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