Nitro azines. 21. Reactivities and electron structures of 6-nitroazolo[1,5-a]pyrimidines |
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Authors: | A. V. Myasnikov P. A. Torgashev T. L. Pilicheva V. L. Rusinov S. A. Gromova M. G. Trofimova A. V. Velik O. N. Chupakhin |
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Affiliation: | (1) S. M. Kirov Ural Polytechnical Institute, 620002 Ekaterinburg |
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Abstract: | 6-Nitroazolopyrimidines react with the acetonyl anion to give 6-nitro-7-acetonyl-4,7-dihydroazolo[1,5-a]pyrimidines. The reactivity of this class of compounds with respect to charged and uncharged nucleophiles is determined by their aromatic character and the deficit of electron density in the pyrimidine ring, while the direction of attack is determined by the overall charge on fragments of the valence-bonded atoms.For Communication 20 see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 807–813, June, 1993. |
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