Oxidation of 1,3-pentadiene on vanadium containing HZSM-5 |
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Authors: | M. Stoyanova R. Dimitrova Chr Minchev |
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Affiliation: | (1) Institute of Solid State Chemistry, Kutateladze 18, 630128 Novosibirsk, Russia;(2) Ivanovo State Chemical Technological Academy, F. Engels, 7, Ivanovo, Russia |
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Abstract: | The possibility of mechanochemical promotion of skeletal nickel catalysts has been shown with the use of mechanical Ni−Al−Mo alloys as Raney nickel precursors in hydrogenation reactions. The mechanochemical promotion makes it possible to introduce molybdenum atoms into the catalyst lattice in the form of a solid solution. These catalysts are more active than pyrometallurgical ones. The increased activity of the catalysts in explained by changes in the structure and energetic state of the catalyst surface |
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Keywords: | Mechanochemistry Raney nickel promotion activity |
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