Deprotonation-electrophile trapping of terminal epoxides |
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| Authors: | Hodgson David M Kirton Eirene H M Miles Steven M Norsikian Stéphanie L M Reynolds Nigel J Coote Steven J |
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| Affiliation: | Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UKOX1 3TA. |
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| Abstract: | Organolithium-induced deprotonation of terminal epoxides in the presence of appropriate diamine ligands allows trapping with a range of electrophiles, yielding functionalised di- and tri-substituted epoxides in good yields and with control of stereochemistry at the epoxide. |
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