[RhCl(CO)(PPh3)]2. A precursor for the synthesis of cationic rhodium complexes with nitrogen donor ligands |
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| Authors: | Rafael Usón Luis A Oro Daniel Carmona Maria Pilar Lamata |
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| Institution: | (1) Department of Inorganic Chemistry, University of Zaragoza, Zaragoza, Spain |
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| Abstract: | Summary The use of RhCl(CO)(PPh3)]2 as a precursor for the synthesis of complexes of the types Rh(CO)L2(PPh3)]A (A = ClO4]– or BPh4]–; L = pyridine type ligand) and Rh(CO)(L-L)(PPh3)]A (A = ClO4]– or BPh4]–; L-L = bidentate nitrogen donor) and the preparation of several complexes of the types Rh(CO)L(PPh3){P(p-RC6H4)3}]BPh4 and Rh(CO)(phen)(PPh3){P(p-RC6H4)3}]A (A = ClO4]– or BPh4]–; R = H or Me) is described.Author to whom all correspondence should be directed. |
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