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Synthesis, Characterization and Conductivity of α-Keggin-type Nanoparticles, Co(en)_3PMo_(12)O_(40)·8H_2O with Optical Activity
作者姓名:HUANG Ru-dan 1**  LI Juan 2  3 and ZHANG Jing1 1. Department of Chemistry  School of Science  Beijing Institute of Technology  Beijing 100081  P. R. China   2. Key Laboratory of Rare Earth Chemistry and Physics  Changchun Institute of Applied Chemistry  Chinese Academy of Sciences  Changchun 130022  P. R. China   3. Department of Chemistry  Normal College  Beihua University  Jilin 132013  P. R. China
作者单位:HUANG Ru-dan 1**,LI Juan 2,3 and ZHANG Jing1 1. Department of Chemistry,School of Science,Beijing Institute of Technology,Beijing 100081,P. R. China; 2. Key Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,P. R. China; 3. Department of Chemistry,Normal College,Beihua University,Jilin 132013,P. R. China
基金项目:Supported by the National Natural Science Foundation of China(No.2 0 3710 0 7)
摘    要:IntroductionChirality is ubiquitous in the nature.Chiralcompounds have many applications in the areas ofmedicine,catalysis and materials,etc. Polyox-ometallates are inorganic polymers,which have at-tracted much interest since they have electri-cal[1_ 3 ] ,magnetic[4] ,optical properties[5_ 7] ,andsome characters as liquid crystals[8,9] .In this workwe report theα- Keggin structural polyoxometallatenanoparticles with optical activities.The opticalactivities of the samples are [α]13 D =+ 1 7…

关 键 词:Polyoxometallates   Nanoparticles   α-Keggin structure   Optical activity
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