Halogen oxidation of mixed amine(tricarbonyl)chromiums |
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| Authors: | Satish C. Tripathi Satish C. Srivastava Chandra P. Singh |
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| Affiliation: | (1) Department of Chemistry, University of Gorakhpur, Gorakhpur, U.P., India |
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| Abstract: | Summary Bromine and iodine oxidation of some mixed amine-(tricarbonyl)chromiums Cr(CO)3(L-L)(amine) (L-L=o-phen or 2,2 -bipy; amine=cyclohexylamine, piperidine and n-butylamine), at ambient temperature lead to the formation of [Cr(CO)2(L-L)(amine)Br]Br3 and [Cr(CO)2(L-L)(amine)I]I complexes which have been characterised by elemental analysis, i.r. spectra, conductivity and magnetic moment measurements. |
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