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Synthesis, Characterization and Properties of Poly(aryl amides) Containing Methoxy Substituted Phthalazinone Moiety
作者姓名:Pei  WANG  Jian  Dong  LIU  Xi  Gao  JIAN
作者单位:Department of Polymer Science & Materials, Dalian University of Technology, Dalian 116012
摘    要:A novel aromatic diamine, 1, 2-dihydro-2-(4-aminophenyl)-4-3-methoxy-4-(4-aminophenoxy)]-2, 3-phthalazin-l-one (OO-DA) containing aza heterocyclic structure was synthesized from the bisphenol-like monomer in two steps and used for preparing new aromatic polyamides with high inherent viscosity of 0.89-1.03 dL.g^-1. The structures of diamine and polymers obtained were confirmed by MS, PT-IR, WAXD and ^1H-NMR. The synthesized polymers exhibited high glass transition temperature in the range of 281-307℃ and good solubility in polar solvents.

关 键 词:聚酰胺  溶解性  合成方法  结构表征  聚氨基化合物
收稿时间:2005-01-14

Synthesis, Characterization and Properties of Poly(aryl amides) Containing Methoxy Substituted Phthalazinone Moiety
Pei WANG Jian Dong LIU Xi Gao JIAN.Synthesis, Characterization and Properties of Poly(aryl amides) Containing Methoxy Substituted Phthalazinone Moiety[J].Chinese Chemical Letters,2005,16(10):1324-1326.
Authors:Pei;WANG;Jian;Dong;LIU;Xi;Gao;JIAN
Abstract:
Keywords:Poly(ether amide) s  phthalazinone  solubility  
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