Ne3-NH3 van der Waals tetramer: rotational spectra and ab initio study of the microsolvation of NH3 with rare gas atoms

Microwave rotational spectra of eleven isotopomers of the Ne(3)-NH(3) van der Waals tetramer were measured using a pulsed jet, Balle-Flygare type Fourier transform microwave spectrometer. The transitions measured fall between 4 and 17 GHz and correspond to the ground internal rotor state of the weakly bound complex. The (20)Ne(3)- and (22)Ne(3)-containing species are symmetric top molecules while the mixed (20)Ne(2)(22)Ne- and (20)Ne(22)Ne(2)-isotopomers are asymmetric tops. For each of the deuterium-containing isotopomers, a tunneling splitting was observed due to the inversion of NH(3) within the tetramer. The (14)N nuclear quadrupole hyperfine structures were resolved and included in the spectroscopic fits of the various isotopomers. The rotational constants obtained from the fits were used to estimate the van der Waals bond lengths of the tetramer while the (14)N nuclear quadrupole coupling contants and the observed inversion tunneling splittings provided information about the internal dynamics of the NH(3) moiety. The experimental results were complemented by the construction of three ab initio potential energy surfaces CCSD(T)] for the Ne(3)-NH(3) complex, each corresponding to a different internal geometry of NH(3) ( 90 degree angle HNH = 106.67 degrees, 90 degree angle HNH = 113.34 degrees, and 90 degree angle HNH = 120.00 degrees ). The topologies of the surfaces are related to the structures and dynamics of the tetramer. Extensive comparisons are made between the results obtained for the Ne(3)-NH(3) tetramer in this work and previous experimental and ab initio studies of related Rg(n)-NH(3) van der Waals clusters.