Metal-Containing Phthalocyanines Substituted with One Branched Bulky Moiety and Six Alkylthio Groups |
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Authors: | Bayır Zehra Altuntaş Merey Şebnur Hamuryudan Esin |
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Affiliation: | (1) Technical University of Istanbul, Department of Chemistry, TR-80626 Maslak, İstanbul, Turkey, TR |
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Abstract: | Summary. Unsymmetrically substituted metal-phthalocyanines composed of three hexylthio groups and one 1-chloro-3,4-dicyano-6-[2-(2-pyridylmethylamino)phenylthio]benzene moiety was prepared by cyclization of the reactants in the presence of the anhydrous metal salts Zn(CH3COO)2, NiCl2, and CoCl2. The new unsymmetric phthalocyanines are very soluble in common organic solvents. The compounds were characterised by their elemental analyses, IR, 1H NMR, MS and UV/Vis spectra. Corresponding author. E-mail: bayir@itu.edu.tr Received November 27, 2002; accepted (revised) December 2, 2002 Published online May 2, 2003 |
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Keywords: | Keyword. Metal-phthalocyanines unsymmetric. |
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