| Photosensitization of trans-Vitamin D3 to cis-Vitamin D3 in Heterogeneous System |
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| 引用本文： | YongBinHAN JinPingCHEN YunYanGAO BaiNingLIU GuoQiangYANG YiLI. Photosensitization of trans-Vitamin D3 to cis-Vitamin D3 in Heterogeneous System[J]. 中国化学快报, 2005, 16(7): 871-874 |
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| 作者姓名： | YongBinHAN JinPingCHEN YunYanGAO BaiNingLIU GuoQiangYANG YiLI |
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| 作者单位： | [1]TechnicalInstituteofPhysicsandChemistry,ChineseAcademyofSciences,Beijing100101 [2]KeyLaboratoryofPhotochemistry,InstituteofChemistry,ChineseAcademyofSciences,Beijing100080 |
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| 摘 要： | Two modes of heterogeneous photoisomerization of trans-vitamin D3 to cis-vitamin D3 are described. The occurrence of isomerization on the substrate bounded to the polymeric support gives us the possibility in succession synthesis of 1α-hydroxyvitamin D3. The polymer-bound anthracene can sensitize isomerization of trans-vitamin D3 to cis-vitamin D3 efficiently and ease the separation process.
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| 关 键 词： | 多相体系 光敏作用 反式维生素D3 顺式维生素D3 固相反应 异构化 聚合物结合蒽 |
Photosensitization of trans-Vitamin D3 to cis-Vitamin D3 in Heterogeneous System |
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| Yong Bin HAN,Jin Ping CHEN,Yun Yan GAO,Bai Ning LIU,Guo Qiang YANG,Yi LI Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing Key Laboratory of Photochemistry. Photosensitization of trans-Vitamin D3 to cis-Vitamin D3 in Heterogeneous System[J]. Chinese Chemical Letters, 2005, 16(7): 871-874 |
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| Authors: | Yong Bin HAN Jin Ping CHEN Yun Yan GAO Bai Ning LIU Guo Qiang YANG Yi LI Technical Institute of Physics Chemistry Chinese Academy of Sciences Beijing Key Laboratory of Photochemistry |
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| Affiliation: | Yong Bin HAN1,Jin Ping CHEN1,Yun Yan GAO1,Bai Ning LIU1,Guo Qiang YANG2*,Yi LI1* 1Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing 100101 2Key Laboratory of Photochemistry,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080 |
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| Abstract: | |
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| Keywords: | Heterogeneous photoisomerization vitamin D3 solid phase. |
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