Über Triphosphorsäurederivate des Cyanamids und des Harnstoffs |
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Authors: | W. Feldmann,H. K hler |
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Affiliation: | W. Feldmann,H. Köhler |
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Abstract: | Triphosphoric Acid Derivatives of Cyanamide and Urea Cyanamidotriphosphate, P3O9NCN5? ( I ), is obtained by ring opening reaction of the cyclotriphosphate ion, P3O93?, by cyanamide in alkaline solution. As a pseudochalcogeno-substituted triphosphate, I has similar properties like the triphosphate, P3O105? (Ca2+ sequestering; behaviour on acidimetric titration; X-ray powder diffraction of the sodium salt hydrates). In acidic solution I decomposes forming ureidotriphosphate with the anion P3O9NHCONH24? ( II ) which cannot be directly obtained from cyclotriphosphate and urea. II is characterized by its chemical analysis, by paper chromatography, by its behaviour in acidic solution and by its IR and 31P-NMR spectra. Solid salts of I and II are prepared and the data of their Guinier diagrams are communicated. |
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