Solvolysis of palladium(II) and platinum(II) complexes of asymmetric ligands: Synthesis and structural characterization of [Pd(AMP)(dmso)Cl]BF4 and [Pt(AMP)(dmso)Cl]ClO4 |
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| Authors: | Tallal Al-Allaf Paule Castan Reine Turpin Smita Wimmer Gerald Bernardinelli |
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| Institution: | 1. Laboratoire de Chimie Inorganique, Universite Paul Sabatier, 118 route de Narbonne, Toulouse, France
3. Laboratoire de Cristallographie, 24 quai Ernest Ansermet, Geneve, Switzerland
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| Abstract: | Treatment of M(AMP)Cl2] (M = PtII, PdII; AMP = 2-aminomethylpyridine) with 1 mole of AgX (X = ClO4, BF4, PF6) in dmso yields M(AMP)(dmso)Cl]X. Single crystal X-ray structure determinations of the PdII and PtII complexes indicate that dmso is S-bondedtrans to the pyridyl ring in both complexes.
(2-Aminomethylpyridine)chloro(dimethylsulphoxide-S) palladium(II) tetrafluoroborate. |
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