Nucleation-controlled multiphase transitions |
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Authors: | Ziabicki Andrzej |
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Institution: | Institute of Fundamental Technological Research, Polish Academy of Sciences, 21 Swietokrzyska Street, 00-049 Warsaw, Poland. aziab@ippt.gov.pl |
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Abstract: | Thermodynamics and kinetics of phase transitions in multiphase systems have been discussed. Thermodynamically admissible transitions have been identified and transition kinetics described in terms of the extended Kolmogoroff-Avrami-Evans model. Different combinations of transitions have been described as directed graphs. Graph nodes represented individual phases, graph edges--transitions. Superposition of parallel transitions in various mother phases, simultaneous transition of the same mother phase into different target phases, and successive (chain) transitions have been analyzed. Detailed solutions for a three-phase system consisting of one liquid phase and two polymorphic solid phases have been presented. |
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