Synthesis and properties of tris[tris (trimethylsilylmethyl) stannyl] thallium |
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Authors: | G S Kalinina E A Shchupak N S Vyazankin G A Razuvaev |
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Institution: | 1. Institute of Chemistry, Academy of Sciences of the USSR, Gorkii
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Abstract: | 1. |
Tristris(trimethylsilylmethyl)stannyl]- and tristris(trimethylsilylmethyl)germyl] thallium, the first stable compounds containing Sn-Tl and Ge-Tl bonds, have been prepared by the reaction of the hydrides of tris (trimethylsilylmethyl)tin and tris (trimethylsilylmethyl)germanium with triethylthallium.
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The Sn-Tl bond is attacked in the reactions of the stannylthallium compound with lithium, mercury, oxygen, bromine, ethyl bromide, ethanol, and other reagents.
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