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| 无溶剂中性条件下分子I2或Fe(NO3)3·9H2O/NaI原位生成的I2催化醇与甲酸甲酰化反应 | |
| 作者姓名： | Rostami AMIN Khazaei ARDESHIR Alavi-Nik HEIDAR ALI Toodeh-Roosta ZAHRA |
| 作者单位： | 1 Department of Chemistry, Faculty of Science, University of Kurdistan, Zip Cod 66177-15175, Sanandaj, Iran; 2 Faculty of Chemistry, Bu-Ali Sina University, Zip Cod 65178-38683, Hamadan, Iran |
| 基金项目： | Supported by Bu-Ali Sina University and University of Kurdistan Research Councils |
| 摘 要： | Different alcohols were formylated by formic acid under solvent-free conditions in the presence of iodine as the catalyst with good-to-high yields at room temperature. I2 generated in situ from Fe(NO3)3·9H2O/NaI also catalyzed the formylation of the alcohols under solvent-free conditions. This gives a green and efficient reaction at room temperature, in which the use of toxic and corrosive molecular I2 is avoided. |
| 关 键 词： | alcohol formic acid formylation iodine in situ iodine solvent-free |
| 收稿时间： | 2010-06-13 |
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