Influence des marches atomiques sur le transport de matière à la surface du nickel

Surface atomic transport on Ni was measured by mass transport technique on a sinusoidal profile. One of the studied surfaces was within 15' of a singular (001) orientation. Others were vicinal surfaces. Kinetic damping coefficients $\text{1}\text{τ}$ are shown to be dependent on the profile parameters, i.e. of the density n_tot, of all the monoatomic steps and also of the density σ_c of kinks of the monoatomic steps. If the parameter describes the random motion of adatoms on isolated terraces and if α and k are two coefficients linked to adsorption/emission processes from steps and kinks, a sinusoidal profile with 5 μm periodicity obeys to the relation: $\text{1}\text{τ}\text{= (}\text{1}\text{τ}\text{)}{}_{\mathrm{T}}\text{[1+αn}{}_{\mathrm{tot}}{}^2\text{(1+ kσ}{}^2{}_{\mathrm{c}}\text{)]}$. This result demonstrates the importance of surface atomic structure which has been neglected in Mullins' theory, which may be non-negligible in all processes where surface mass transport is involved.