The biosynthetic origin of fusicoccin hydroxyisopropyl group |
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Authors: | A Evidente G Randazzo |
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Institution: | Istituto de Chimica Organica e Biologica, Università di Napoli, Via Mezzocannone, 16, 80134 Napoli, Italy |
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Abstract: | The biosynthetic origin of the hydroxyisopropyl group of fusicoccin 1 has been determined. Two out of the eight tritium mevalonoid atoms retained in 1 following incorporation of MVA-2-3H2,2-14C] have been located at C-20; whilst none has been found in the C-19 methylene group. |
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