Synthesis of optically active forms of (E)-6-isopropyl-3,9-dimethyl-5,8-decadienyl acetate,the pheromone of the yellow scale |
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Authors: | Kenji Mori Shigefumi Kuwahara |
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Affiliation: | Department of Agricultural Chemistry, The University of Tokyo, Yayoi 1-1-1, Bunkyo-ku, Tokyo 113, Japan |
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Abstract: | Highly optically pure enantiomers of (E)-6-isopropyl-3,9-dimethyl-5,8-decadienyl acetate, the sex pheromone of the yellow scale (Aniodiella citrina), were stereoselectively from synthesized from(R)-(+)-citronellic acid. Only the (s)-enantiomer was bioactive. |
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