Comments on the dynamical properties of iron pentacarbonyl,Fe(CO)5, adsorbed on (0001) graphite |
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| Authors: | H Shechter R Brener J Suzanne |
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| Institution: | Physics and Solid State Institute, Technion-Israel Institute of Technology, Haifa 32000, Israel;Département de Physique, Faculté des Sciences de Luminy, F-13288 MarseilleCedex 9, France |
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| Abstract: | A fraction of a monolayer of Fe(CO)5 was deposited on a clean Papyex stack following an adsorption vapor pressure isotherm. Mössbauer spectra for kγ parallel and perpendicular to the film surface yield evidence of a first-order phase transition at T ～- K. The asymmetry of the spectrum suggests a possible average list of the molecular axis of ~50° to the surface normal. |
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