Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids |
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| Authors: | Lautens Mark Dockendorff Chris Fagnou Keith Malicki Adrianna |
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| Institution: | Davenport Laboratories, Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5H 3H6. mlautens@chem.utoronto.ca |
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| Abstract: | The first rhodium(I)-catalyzed asymmetric addition of organoboronic acids to oxabicyclic alkenes is reported. This asymmetric ring-opening (ARO) reaction can proceed in high yield under very mild conditions with electronically diverse organoboronic acids, in a highly diastereoselective and enantioselective manner. structure: see text] |
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