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Preparation and Electrochemical Characteristics of Three-dimensional Manganese Oxide Micro-supercapacitor Electrode
Authors:Chun-ming Wen  Zhi-yu Wen  Zheng You  Xiao-feng Wang
Affiliation:1.Key Laboratory of Fundamental Science on Micro/Nano-Device and System Technology, Chongqing University, Chongqing 400030, China;Microsystem Research Center, Chongqing University, Chongqing 400030, China2.Department of Precision Instruments and Mechanics, Tsinghua University, Beijing 100084, China
Abstract:In order to increase the electrode surface area and enhance the charge storage capacity, we study the micro electro mechanical system technology to fabricate three-dimensional high aspect ratio micro-electrode structure based on glass. The anodic constant potential method is employed to deposit manganese oxide as electroactive substances on the micro-electrode surface. Cyclic voltammetry and constant current charge-discharge method are both used to prepare electrode electrochemical performance testing, with a two-dimensional electrode without structure for comparison. Experimental results show that three-dimensional elec-trode structure can effectively enhance the charge storage capacity. At 1.0 mA/cm2 charge-discharge density, the three-dimensional electrode shows a capacitance of 17.88 mF/cm2, seven times higher than the two-dimensional electrode.
Keywords:Micro-supercapacitor   Micro electro mechanical system   Three-dimensional electrode   Manganese oxide
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