On the use of remote RF plasma source to enhance III–V MOCVD technology |
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Authors: | G. Bruno M. Losurdo P. Capezzuto |
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Affiliation: | Centro di Studio per la Chimica dei Plasmi, CNR, Dipartimento di Chimica-Università di Bari, via Orabona 4, I-70126, Bari, Italy |
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Abstract: | A remote RF (13.56 MHz) plasma source, assembled on a metalorganic chemical vapour deposition (MOCVD) system, was used to investigate the processes of (a) cleaning and passivation of InP substrates with H atoms (H2 plasmas), (b) deposition of InP epilayers from In(CH3)3 and PHx radicals (PH3/H2 plasmas), and (c) deposition of InN on sapphire from In(CH3)3 and N atoms (N2---H2---Ar plasmas). From kinetic and spectroscopic ellipsometric in situ analysis, the removal of native oxide from InP surface was found to be complete, without surface damage (phosphorus depletion), at 230°C and 7 min of H atoms exposure. The growth of InP epilayers with PH3 plasma pre-activation was successful (stoichiometric InP) even at low V/III ratio. During InN growth, the use of optical emission spectroscopy (OES) and of in situ ellipsometry (SE) was determinant for the process control. |
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