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Electron-hole mechanism for the decomposition of zinc sulfide in a hydrogen atmosphere
Authors:V. F. Kharlamov  V. V. Styrov  A. P. Il'in  I. Z. Gorfunkel'
Affiliation:(1) S. M. Kirov Tomsk Polytechnic Institute, USSR
Abstract:Chemical analysis is used to study the structural changes on the surface of a ZnS-Cu, Pb phosphor arising in the course of photoluminescence in molecular hydrogen and radical-recombination luminescence excited by hydrogen atoms. The photolysis of zinc sulfide and its decomposition by an atomic-molecular mixture of hydrogen were observed. A mechanism for the reduction involving electrons, holes, and chemisorbed hydrogen is discussed.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 42–46, October, 1976.
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