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Evidence of defect associates in yttrium-stabilized zirconia
Authors:Z Wang  Z Q Chen  J Zhu  S J Wang  X Guo
Institution:

a Department of Physics, Wuhan University, Wuhan, 430072, People's Republic of China

b Department of Material Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, People's Republic of China

Abstract:After Nb2O5 was added to Y2O3-stabilized ZrO2, the bulk conductivity decreased distinctly. Positron annihilation lifetime and Doppler broadening spectra were measured to study the effects of Nb2O5 on electrical properties of Y2O3-stabilized ZrO2. The result shows that the additions of Nb2O5 can decrease the V2+O concentration and increase the (YZrV2+OYZr)0 concentration, which is why bulk conductivity decreases. The additions of Nb2O5 were expected to suppress the formation of defect associates, however, only adverse experimental results were found in the present work.
Keywords:
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