a Department of Physics, Wuhan University, Wuhan, 430072, People's Republic of China
b Department of Material Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, People's Republic of China
Abstract:
After Nb2O5 was added to Y2O3-stabilized ZrO2, the bulk conductivity decreased distinctly. Positron annihilation lifetime and Doppler broadening spectra were measured to study the effects of Nb2O5 on electrical properties of Y2O3-stabilized ZrO2. The result shows that the additions of Nb2O5 can decrease the V2+O concentration and increase the (Y−ZrV2+OY−Zr)0 concentration, which is why bulk conductivity decreases. The additions of Nb2O5 were expected to suppress the formation of defect associates, however, only adverse experimental results were found in the present work.